Reagents and synthetic methods. 31. Silylations with N-trimethylsilyl-2-oxazolidinone (TMSO)

Dudley Benzylation Reagent Trichloroacetimidate Reagents (2-trimethylsilyl)- Ethanesulfonyl Reagents Ethynylnaphthalenes Fluorous Protecting Groups Common Reagents for Protection Common Reagents for Deprotection

Organometallic uranium(IV) fluoride complexes: preparation using protonolysis chemistry and reactivity with trimethylsilyl reagents.

Reaction of the uranium alkyl complex (C(5)Me(5))(2)UMe(2) (1) with Et(3)N.3HF in toluene in the presence of a donor ligand (pyridine or trimethylphosphine oxide) results in gas evolution and the formation of the uranium(IV) difluoride complexes (C(5)Me(5))(2)UF(2)(L) (L = NC(5)H(5) (2), Me(3)P=O (3)). Similarly, reaction of (C(5)Me(5))(2)U[kappa(2)-(C,N)-CH(2)Si(CH(3))(2)N(SiMe(3))] (5) with E...

[η5-2,3-Bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(N,N,N′,N′-tetramethylethylenediamine)dysprosium(III)

The structure of the title compound, [Dy(C(8)H(22)B(4)Si(2))Cl(C(6)H(16)N(2))], reveals that a center of symmetry exists within the dimeric half-sandwich units. Within each half-sandwich, the Dy(III) ion is coordinated by the five-membered ring of the carborane, tetramethylethyl-enediamine and the chloride ion.

Why are trimethylsilyl groups asymmetrically coordinated? Gas-phase molecular structures of 1-trimethylsilyl-1,2,3-benzotriazole and 2-trimethylsilyl-1,3-thiazole.

The structures of 1-trimethylsilyl-1,2,3-benzotriazole and 2-trimethylsilyl-1,3-thiazole have been determined by gas electron diffraction and computational methods. While 1-trimethylsilyl-1,2,3-benzotriazole shows a significant asymmetry in the way the SiMe(3) groups bonds to the ring system, the same is not true for 2-trimethylsilyl-1,3-thiazole. However, it has been shown that when the positi...

Competing [ 2 + 31 and [ 4 + 31 Cycloadditions of C , N - Diphenylnitrone with 1 , 3 - Dienes . Evidence for Thermally Nonequilibrated Intermediatest

at -78 "C for 4 h. To the mixture was added a solution of compound 14 (5.0 mmol) and AlCl, (5.0 mmol) in CH2C12 (15 mL) dropwise. The mixture was stirred at -78 "C for 4 h and allowed to warm to room temperature. The mixture was hydrolyzed with water and extracted three times with ether. The ether phase was washed with brine, dried (MgSO,), and filtered. The filtrate was evaporated and the resi...